Here are the steps to setup a POP3 account for hotmail on your android phone
1. Click on Add Account
a. Enter Full username
b. Enter password
Click on Manual Setup
2. Incoming POP3 Mail Server Setting :
User Name : user@hotmail.com
Password : your email password
Incoming Mail Server/Pop3 Server : pop3.live.com
Port : 995
Security Type : SSL
Click on Next.
If settings are OK and password is valid, you will be asked to enter outgoing mail server settings-
3. Outgoing POP3 Mail Server Setting :
Outgoing Mail Server/SMTP Server : smtp.live.com
Port : 587
Security (Port)/Security Type : SSL/TLS
User Name : user@hotmail.com
Password : your email password
4. Configure Account options as you want.
5. Set up an account name for this account.
That's it!